Synchrotron IR study of hydrous ringwoodite (γ-Mg2SiO4) up to 30 GPa     

E. M. Chamorro Pérez  I. Daniel  J.-C. Chervin  P. Dumas  J. D. Bass  T. Inoue 《Physics and Chemistry of Minerals》2006,33(7):502-510

High-pressure synchrotron infrared (IR) absorption spectra were collected between 650 and 4,000 cm⁻¹ at ambient temperature for hydrous Mg-ringwoodite (γ-Mg₂SiO₄) up to 30 GPa. The main feature in the OH⁻ stretching region is an extremely broad band centred at 3,150 cm⁻¹. The hydrogen bond is strong for most protons and the most probable site for protonation is the tetrahedral edge. With increasing pressure, this band shifts downward while decreasing its integrated intensity until disappearance at a pressure of 25 GPa. Only one band at 2,450 cm⁻¹ and an absorption plateau persist with a maximum wavenumber of 3,800 cm⁻¹. This behaviour is reversible upon pressure release. We interpret this as a second-order phase transition occurring in hydrated Mg-ringwoodite at high pressure (beyond ∼ 25 GPa). This result is compatible with the observation by Kleppe et al. (Phys Chem Miner 29:473–476, 2002a) who suggested the presence of Si–O–Si linkages and/or partial increase in the coordination of Si. Beyond the phase transition, the protons are delocalized and their environment on the ringwoodite structure is probably quite different from that at low pressure. Data obtained in situ at high pressures and temperatures are needed to better understand the effect of protonation on the structure and to better constrain this phase transition.  相似文献   

攀枝花地区基性-碱性岩系Th、Ta、Hf地球化学特征     

刘峰  张成江  汪云亮  施泽明 《物探化探计算技术》2005,27(1):43-47

攀枝花地区的基性—碱性岩系,是一套与钒钛磁铁矿、稀土矿、铍、钪、镓等多种矿产有关的含矿岩浆岩系。该岩系的Th、Ta、Hf地球化学特征极为相似,其Th/Hf比值在0.3～1.0之间,Ta/Hf比值更为接近,在0.2～0.5之间。在Th/Hf-Ta/Hf双对数图上,该岩系的源区特征和演化特征非常明显。此结果与峨嵋山地区的玄武岩和会东地区的基性岩系对比,Th、Ta、Hf特征都十分相近,因此该区原来被认为是两个地质时期(华力西期与印支期)的岩系,实际上是同一地质时期(华力西晚期)同源但不同阶段的产物,均是与峨嵋地幔柱关系密切的峨嵋玄武岩浆演化的结果。  相似文献   

云南三江口地区超基性岩岩石化学及成因   总被引：1，自引：0，他引：1  

俞赛赢  杨仕潘 《云南地质》2005,24(1):83-88

三江口地区超基性岩按岩石类型可分六种,岩石的m/f值小于6 5,属铁质超基性岩,呈包体状产于下二叠统木星土岩组(P1mx.)及上二叠统洛吉组(P2lj)中,与其为同源异相产物,形成于板块裂陷环境。岩浆活动时期大致为晚古生代 早三叠世早期,可能代表古特提斯形成的早期阶段。成果为进一步研究和恢复该区古构造格局提供重要依据。  相似文献   

川西北松潘-甘孜地块大石包组玄武岩成因及其形成构造背景   总被引：9，自引：0，他引：9  

肖龙  许继峰 《岩石学报》2005,21(6):1539-1545

川西北松潘-甘孜地块内二叠世大石包组玄武岩富集大离子亲石元素和高场强元素，具有与洋岛玄武岩相似的地球化学性质，形成于大陆板内环境。通过与典型峨眉山玄武岩之地球化学组成的对比研究，认为大石包玄武岩与峨眉山玄武岩中的高钛类玄武岩性质相同，两者具有一个共同的成因，即都是峨眉山地幔柱活动的产物。由此推测峨眉山玄武岩不仅分布在扬子地块内部，向西还有一定的延伸，同时暗示了峨眉山地幔柱头部可能具有比现在所认识的更大的规模。  相似文献   

峨眉山玄武岩的地幔热柱成因   总被引：32，自引：4，他引：32  

宋谢炎  侯增谦  汪云亮  张成江  曹志敏  李佑国 《矿物岩石》2002,22(4):27-32

根据峨眉山玄武岩的岩石组合、岩相学特征将峨眉火成岩省分为盐源-丽江岩区、攀西岩区、贵州高原岩区和松潘-甘孜岩区。通过对研究区二叠世的区域地质背景和古地理环境的分析，对峨眉山玄武岩喷发与地幔热柱的关系及其火山喷发的大地构造背景进行了进一步系统归纳和总结。根据地层学关系大致确定峨眉山玄武岩的主喷发期是阳新世（中二叠）晚期-乐平世（晚二叠）早期，时限大致为259Ma-257Ma。峨眉山玄武岩微量元素地幔标准化曲线特征与OIB基本一致，反映出其成因与地幔热柱活动有密不可分的关系。  相似文献   

地幔热柱及其成矿作用研究     

牛树银  孙爱群  谢汝斌  许传诗  王宝德  杨志宏  毕伏科  孙冀凡 《华北地质》2002,25(1):11-22

成矿作用研究表明 ,在地球的演化历史中 ,成矿数量有从少到多 ,聚矿能力有由弱到强的演化趋势。中生代为全球规模的成矿大爆发阶段 ,究其原因可能与地球的发展演化密切相关。地球形成的早期 ,由于地球物质尚未充分分异 ,成矿强度不大。当然 ,有部分在地球演化早期形成的矿床 ,在后来的多次构造改造过程中被改造迁移 ,甚至消失。中生代地球进入了一个强烈的地幔热柱活动时期 ,聚集于D”层及外核的成矿物质可通过地幔热柱多级演化向上迁移 ,并在幔枝构造的有利构造扩容带中成矿 ,幔枝构造则成为中生代主要的成矿控矿构造类型  相似文献   

Mantle structure and rifting processes in the Baikal–Mongolia region: geophysical data and evidence from xenoliths in volcanic rocks     

Dmitri Ionov   《Tectonophysics》2002,351(1-2)

The origin of the Baikal rift zone (BRZ) has been debated between the advocates of passive and active rifting since the 1970s. A re-assessment of the relevant geological and geophysical data from Russian and international literature questions the concept of broad asthenospheric upwelling beneath the rift zone that has been the cornerstone of many “active rifting” models. Results of a large number of early and recent studies favour the role of far-field forces in the opening and development of the BRZ. This study emphasises the data obtained through studies of peridotite and pyroxenite xenoliths brought to the surface by alkali basaltic magmas in southern Siberia and central Mongolia. These xenoliths are direct samples of the upper mantle in the vicinity of the BRZ. Of particular importance are suites of garnet-bearing xenoliths that have been used to construct P–T- composition lithospheric cross-sections in the region for the depth range of 35–80 km.Xenolith studies have shown fundamental differences in the composition and thermal regime between the lithospheric mantle beneath the ancient Siberian platform (sampled by kimberlites) and beneath younger mobile belts south of the platform. The uppermost mantle in southern Siberia and central Mongolia is much hotter at similar levels than the mantle in the Siberian craton and also has significantly higher contents of ‘basaltic’ major elements (Ca, Al, Na) and iron, higher Fe/Si and Fe/Mg. The combination of the moderately high geothermal gradient and the fertile compositions in the off-cratonic mantle appears to be a determining factor controlling differences in sub-Moho seismic velocities relative to the Siberian craton. Chemical and isotopic compositions of the off-cratonic xenoliths indicate small-scale and regional mantle heterogeneities attributed to various partial melting and enrichment events, consistent with long-term evolution in the lithospheric mantle. Age estimates of mantle events based on Os–Sr–Nd isotopic data can be correlated with major regional stages of crustal formation and may indicate long-term crust–mantle coupling. The ratios of ^143/144Nd in many LREE-depleted xenoliths are higher than those in MORB or OIB source regions and are not consistent with a recent origin from asthenospheric mantle.Mantle xenoliths nearest to the rift basins (30–50 km south of southern Lake Baikal) show no unequivocal evidence for strong heating, unusual stress and deformation, solid state flow, magmatic activity or partial melting that could be indicative of an asthenospheric intrusion right below the Moho. Comparisons between xenoliths from older and younger volcanic rocks east of Lake Baikal, together with observations on phase transformations and mineral zoning in individual xenoliths, have indicated recent heating in portions of the lithospheric mantle that may be related to localised magmatic activity or small-scale ascent of deep mantle material. Overall, the petrographic, P–T, chemical and isotopic constraints from mantle xenoliths appear to be consistent with recent geophysical studies, which found no evidence for a large-scale asthenospheric upwarp beneath the rift, and lend support to passive rifting mechanism for the BRZ.  相似文献   

Cascaded Evolution of Mantle Plumes and Metallogenesis of Core- and Mantle-derived Elements   总被引：1，自引：0，他引：1  

NIU Shuyin  HOU Quanlin  HOU Zengqian  SUN Aiqun  WANG Baode  LI Hongyang  XU Chuanshi Institute of Geology  Geological Survey  Shijiazhuang College of Economics  Shijiazhuang  Hebei  Institute of Geophysics  Chinese Academy of Sciences  Beijing Institute of Mineral Resources  Chinese Academy of Geological Sciences  Beijing 《《地质学报》英文版》2003,77(4):522-536

Mineral deposits are unevenly distributed in the Earth's crust, which is closely related to the formation and evolution of the Earth. In the early history of the Earth, controlled by the gravitational contraction and thermal expansion, lighter elements, such as radioactive, halogen-family, rare and rare earth elements and alkali metals, migrated upwards; whereas heavier elements, such as iron-family and platinum-family elements, base metals and noble metals, had a tendency of sinking to the Earth's core, so that the elements iron, nickel, gold and silver are mainly concentrated in the Earth's core. However, during the formation of the stratified structure of the Earth, the existence of temperature, pressure and viscosity differences inside and outside the Earth resulted in vertical material movement manifested mainly by cascaded evolution of mantle plumes in the Earth. The stratifications and vertical movement of the Earth were interdependent and constituted the motive force of the mantle-core movement.  相似文献   

辽宁地区的幔枝构造          下载免费PDF全文

白永俊  夏洪宝  赵艳秋 《地质找矿论丛》2003,18(Z1):1-6

将辽宁地区划分为4个幔枝构造:山海关幔枝、辽东南幔枝、建平-阜新幔枝、西丰幔枝,文章分述了它们各自组成与构造特点,并举例说明了辽宁幔枝构造通过其三个次级构造单元对成矿的控制规律.  相似文献   

云南保山卧牛寺组玄武岩成因：地幔柱活动的产物？   总被引：3，自引：0，他引：3       下载免费PDF全文

肖龙徐义刚  梅厚钧于荣萍 《岩石矿物学杂志》2003,22(1):20-28

保山卧牛寺组玄武岩为低钛拉斑玄武岩，具有大陆板内玄武岩的特征，总体与蛾眉山玄武岩中的低钛玄武岩相似。其分异程度较高，富集大离子亲石元素和高场强元素，有明显的Nb、Ta负异常，Zr和Hf正异常，Eu无异常或弱负异常。该玄武岩由3个大喷发旋回形成3个岩石单元，其中下部早期第1单元由致密块状玄武岩、斜斑玄武岩、杏仁玄武岩和凝灰岩组成，第2和第3单元中见少量橄榄玄武岩和粒玄岩以及辉绿岩脉。有较高的^86Sr／^87Sr值(0．705966—0．706657)、较低的^143Nd／^144Nd值(0．512212—0．512283)，εNd(t)多为负值，源区为介于EMI和EMⅡ端员之间的富集岩石圈地幔。上述地球化学和同位素特征均可与蛾眉山玄武岩下部低钛拉斑玄武岩对比，表明该期岩浆作用可能同为地幔柱活动的产物，并暗示蛾眉山大火成岩省向西有很大的延伸。  相似文献